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Methyl tert-butyl ether

CAS 1634-04-4C5H12O88.15 g/mol

Methyl tert-butyl ether is an ether having methyl and tert-butyl as the two alkyl components. It has a role as a metabolite, a non-polar solvent and a fuel additive.

IUPAC: 2-methoxy-2-methylpropane

Methyl tert-butyl ether molecular structure

PubChem

Physical & Chemical Properties

Physical and chemical properties
Melting Point-164.2 °F (USCG, 1999)
Boiling Point131.4 °F at 760 mmHg (USCG, 1999)
Density0.7405 at 68 °F (USCG, 1999) - Less dense than water; will float
SolubilitySolubility of water in methyl t-butyl ether: 1.5 g/100 g; unstable in acid solution
Flash Point-14 °F (USCG, 1999)
Vapor Pressure250.0 [mmHg]
AppearanceMethyl tert-butyl ether appears as a colorless liquid with a distinctive anesthetic-like odor. Vapors are heavier than air and narcotic (cause drowsiness when inhaled). This liquid has a flash point lower than most ambient temperatures, so it will readily ignite under most conditions. It is less dense than water and moderately soluble in water. Used as a octane booster in gasoline.

Data: PubChem · Last updated: 4/20/2026

GHS Classification

No GHS classification data available.

Classification data is sourced from ECHA.

Regulatory Compliance

TSCA

Listed

note: Status based on EPA TSCA Active Inventory · inventory name: TSCA Chemical Substance Inventory

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SVHC

Not Listed

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FDA GRAS

Not Listed

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HS Code(s): 2909

Data: UN Comtrade

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